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Synthesis And Spectral Studies Of New Schiff Base Macrocyclic Zn(II) Complexes

Hamdi Temel, Salih Ihan

Ten new types of Zn(II) complexes were synthesized by template effect by reaction of 2,6-diaminopyridine with Zn(ClO4)2 .6H2O, Zn(NO3)2 .6H2O and salicylaldehyde derivatives in chloroform-methanol. The complexes have been characterized by elemental analysis, IR, 1H NMR, UV-vis spectra, magnetic susceptibility, conductivity measurements and mass spectra. On the bases of the spectral studies four coordinated tetrahedral geometry may be assigned to these complexes.